There is a little trick to it...
you have to disable the skills so that your hero won't drop them outside combat. Then you have to manually cast them on whoever you are targeting. Last night I set up my heor monk as a bonder and he did it just fine (Bath spirit, Life bond, life barrier). The only thing you have to worry about is that the AI will cast blessed sig as soon as it is ready, which is usually not a big deal but it can be if they waste it when they are only down a few points of energy.
As far as telling them who to target...if you want them to target you, just target yourself and then tell them to cast (while you are targeted) and you are good to go. You can't lock him on a party member but he will always cast on whoever you have targeted at teh time (if possible).
hope that helps
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